Search results for "Spectral shift"
showing 10 items of 10 documents
On-line laser spectroscopy of short-lived mercury isotopes
1978
Huge shift of fundamental electronic absorption edge in Sr1−xBaxNb2O6 crystals at elevated temperatures
1995
Thermostabilization of BSA in TMAO Water Mixtures by Infrared Spectroscopy
2019
Background:Trimethylamine-N-Oxide (TMAO) is a small organic molecule derived from the metabolism of L-carnitine and choline after ingestion of animal food. TMAO has many functions such as electron acceptor, an osmolyte, stabilizer of macromolecules folding. It seems that TMAO plays an important role in nature but, in humans, it is a remnant of the evolution of the osmolyte system.Objective:The present paper is addressed on the study of thermal stability of hydrated Bovine Serum Albumins (BSA) in the presence of water and TMAO water solution by means of InfraRed spectroscopy. In particular, this work has investigated the protein amide I spectral regions, which is sensitive to protein seconda…
Theoretical and Experimental Study of Polarization Modulation Instability in All-Normal Dispersion Photonic Crystal Fibers
2018
Experimental observation of polarization modulation instability in all-normal dispersion photonic crystal fibers is reported. Stokes and anti-Stokes sidebands with spectral shift of 40 nm were observed when the fiber was pumped at 1064 nm. Experimental results are baked by a vectorial four-wave mixing model.
Role of in-medium hadrons in photon–nucleus reactions: shadowing and dilepton spectrum
2003
We study the effect of in-medium hadronic properties in photon nucleus interactions in the context of shadowing as well as the dilepton spectrum for incident photon energies in the range 1.1- 3 GeV. A reasonable agreement with the experimental data for shadowing is obtained in a scenario of downward spectral shift of the hadrons. We show that distinguishable features for in-medium changes of the hadronic properties can be observed experimentally through the dilepton spectrum by judicious choice of target nuclei and incident energy of photons.
Time-resolved coherent anti-Stokes Raman-scattering measurements of I2 in solid Kr: vibrational dephasing on the ground electronic state at 2.6-32 K.
2005
Time-resolved coherent anti-Stokes Raman-scattering (CARS) measurements are carried out for iodine (I2) in solid krypton matrices. The dependence of vibrational dephasing time on temperature and vibrational quantum number v is studied. The v dependence is approximately quadratic, while the temperature dependence of both vibrational dephasing and spectral shift, although weak, fits the exponential form characteristic of dephasing by pseudolocal phonons. The analysis of the data indicates that the frequency of the pseudolocal phonons is approximately 30 cm(-1). The longest dephasing times are observed for v = 2 being approximately 300 ps and limited by inhomogeneous broadening. An increase in…
Die relative Isotopenlage des Os186
1962
Using three different samples of Os192, Os190 and Os186 enriched to 98.68%, 95.46%, and 61.27%, respectively, the isotopic shiftsΔν(Os192−Os190) andΔν(Os192−Os186) have been measured in four Os I-lines with a recording Fabry-Perot spectrometer. The relative isotopic position of Os186 has been found to be $$\frac{{\Delta \nu (Os^{192} - Os^{186} )}}{{\Delta \nu (Os^{192} - Os^{190} )}} = 3.52 \pm 0.03.$$
Collisional broadening and shifting parameters of the RamanQbranch ofH2perturbed byN2determined from speed-dependent line profiles at high temperatur…
1996
The broadening and shifting of the {ital Q} branch of H{sub 2} diluted in N{sub 2} are studied at temperatures between 300 and 1200 K. (i) In order to account for the observed anomalies (asymmetric profiles and nonlinearity of the linewidth versus perturber concentration), the results are interpreted using a speed-dependent model in its general form. This model introduces the speed dependence of the shift and the broadening. In contrast with the previous H{sub 2}{endash}rare-gas studies, the high-temperature measurements prove the necessity to include speed-dependent broadening that was ignored in the previous studies. (ii) Concomitantly, we report as well pure H{sub 2} results including Ra…
Nuclear Shape Staggering in Very Neutron-Deficient Hg Isotopes Detected by Laser Spectroscopy
1977
The isotope shifts of $^{188}\mathrm{Hg}$, $^{186}\mathrm{Hg}$, and $^{184}\mathrm{Hg}$ in the 2537-\AA{} line have been measured by use of tunable dye laser at the on-line mass separator ISOLDE at CERN. The results are $\ensuremath{\delta}\ensuremath{\nu}(^{188}\mathrm{Hg}\ensuremath{-}^{204}\mathrm{Hg})=35.8(2)$ GHz; $\ensuremath{\delta}\ensuremath{\nu}(^{186}\mathrm{Hg}\ensuremath{-}^{204}\mathrm{Hg})=39.4(2)$ GHz; and $\ensuremath{\delta}\ensuremath{\nu}(^{184}\mathrm{Hg}\ensuremath{-}^{204}\mathrm{Hg})=43.1(2)$ GHz. These data combined with those obtained by $\ensuremath{\beta}$-radiation-detected optical pumping ($\ensuremath{\beta}$-RADOP) on the odd Hg isotopes yield a huge odd-even…
SHIFT AND WIDTH OF HeII LINES
1998
Abstract Based on a quantum statistical many-particle theory, the shift and the width of some He II lines have been evaluated. Ion dynamics have been treated within the model microfield method. Furthermore, fine structure splitting has been taken into account in order to check whether this effect is the cause for the existing large discrepancies between theoretical and experimental line widths. Besides the electronic contributions to the line shift, the shift due to the inhomogeneities of the ionic microfield as well as that due to the quadratic Stark effect has been included.